Hazardous decomposition products hydrogen chloride, nickel oxides. Cornell ehs provides campus wide access to chemwatch, an online safety data sheet sds database consisting of over 250,000 chemwatch authored documents, and million vendor supplied documents. Nickelii chloride or just nickel chloride, is the chemical compound nicl 2. Section 1 chemical product and company identification. Transportation information this product is a regulated material for domestic ground transporation, per cfr title 49. American elements can prepare dissolved homogeneous solutions at customer specified concentrations or to the maximum stoichiometric concentration.
Safety data sheets and other chemical safety information are a vailable online. The main cause of concern when handling nickel, its alloys or its salts, is its ability to produce allergic dermatitis. Sigmaaldrich offers a number of nickel ii chloride products. Nickel chloride liquid palms liquid nickel chloride is especially produced for demanding plating and catalyst applications, and is the purest form available commercially. The perfect tool for accomplishing this feat is the material safety data sheet msds. Nickelii chloride, in various forms, is the most important source of nickel for chemical synthesis. Fire or heat will produce irritating, poisonous andor corrosive gases. It is a water soluble compound that crystallizes to form a hexahydrate. They are an excellent source of nickel chloride for applications requiring solubilized materials. Sigmaaldrich offers a number of nickelii chloride products.
It is manufactured to demanding specifications from carefully selected raw materials, and is subjected to stringent quality control testing. Received 3 february 1987 abstract the decomposition of. Nickel chloride hexahydrate classified as hazardous material does not burn. Overexposure by inhalation may result in irritation of the upper respiratory passages with coughing. Crystalbond 555 only available as paper copy, see binder in bard 316. Always check your browsers address bar before you enter your netid password to make sure the address starts with cornell.
Toxicological profile for nickel agency for toxic substances. Material safety data sheet cobaltii chloride hexahydrate. Nickel ii chloride is used in electroplating and as a catalyst for organic conversions, for example in chemoselective thioacetalization of aldehydes. Ferric chloride has been infrequently associated with skin sensitization in humans. Search results for nickel chloride at sigmaaldrich. Specific hazards arising from the chemical hazchem code 2x. Cupric sulfate, ammoniated, 10380297, ammoniated copper sulfate. Ecological information ecotoxicity the product contains following substances which are hazardous for the. Special protective equipment as in any fire, wear mshanioshapproved or equivalent, selfcontained,positive. Nickel acetate ld50 intraperitoneal, mouse 45700 ugkg nickel acetate is listed by the ntp as known human carcinogen as nickel compounds and by the iarc as group known human carcinogen as nickel compounds. One observation in a single dose nickel chloride injection in male rats showed. Use alcoholresistant foam or flood with fine water spray. Cuweblogin is a component of cornell universitys central authentication service. In order for infotrac to provide coverage, your material must be on the sds list.
Thermochimica acta, 118 1987 191197 191 elsevier science publishers b. Carcinogenic to humans nickel chloride, hexahydrate. General description nickel ii chloride nicl 2 is a nickel based halide that is prepared by burning nickel in chlorine. Nickel chloride is on the hazardous substance list because it is regulated by osha and cited by acgih. Identification of the substancemixture and of the company. Persons with preexisting skin disorders, impaired respiratory or pulmonary function, or with a history of asthma, allergies, or sensitization to nickel compounds may be at an increased risk upon exposure to this substance. Nickel ii chloride ld50 175 mgkg rat not listed not listed toxicologically synergistic products no information available delayed and immediate effects as well as chronic effects from short and longterm exposure irritation no information available sensitization may cause sensitization by skin contact. Manganeseii chloride, anhydrous 7773015 98 section 4 first aid measures swallowed if swallowed, refer for medical attention, where possible, without delay. To maintain this coverage cornell provides infotrac with sds information for all hazardous materials shipped.
However, symptoms of systemic toxicity, including severe weight loss, were also observed at the same concentrations indicating copper nickel alloy material safety data sheet accute animal toxicity data type for product for components copper nickel tin zinc iron. For advice, contact a poisons information centre or a doctor. Material safety data sheet msds common name synonym trade name manufactured for validation date in case of emergency. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides. In normal use conditions and in its original form, the product itself does not involve any other risk for health and the environment. Nickel hydroxide carbonate ld50 oral, rat 840 mgkg nickel hydroxide carbonate is listed by the ntp as known human carcinogen as nickel compounds and by the ia as group 1, known human carcinogen as nickel compounds. It acts as a catalyst to prepare dialkyl arylphosphonates from phosphites and aryl iodide. Ingestion may cause corrosive damage to the gl tract repeated. Hazardous combustion potassium oxides, hydrogen chloride. The anhydrous salt is yellow, but the more familiar hydrate nicl 2 6h 2 o is green. Causes nickel itch which is a dermatitis resulting.
Excessive thermal conditions may cause decomposition andyield hazardous combustion products listed above. Safety data sheet 118470 nickelii chloride hexahydrate. It is majorly utilized in organic synthesis as a catalyst and a precursor. Listed as nickel chloride massachusetts spill list. This list of hazardous materials totals over chemicals and is updated as needed. Physical and chemical properties molecular formula na. Get the convenience and safety of a liquid at a price that is competitive to dry nickel chloride. Nickel ii chloride revision date 23jan2018 delayed of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing endocrine disruptor informationno information available other adverse effects the toxicological properties have not been fully investigated. Material safety data sheet western kentucky university.
Deamination of trisethylenediaminenickelii chloride and. Material safety data sheet sodium chloride section 1 chemical product and company identification msds name. This material does not contain any class 1 ozone depletors. Safety data sheet of 6 infosafe no 1ch4n issue date.
Identification ofthe substance preparation and the com any undertaking product name nickel hydroxide chemical namesynonyms nickel hydroxideinorganic salt useofthe substance preparation the product isused in industrial manufacturing, inparticular in. Move container from fire area if it can be done without risk. Whatever your business needs, local or global, univertical will deliver. It is preferred in highend applications such as platingonplastic. Material safety data sheet page 1 of 2 nickel nitrate. Nickelii chloride is a mild lewis acid used for the regioselective isomerization of dienols and selective reduction of alkenes to alkanes in presence of lithium aluminum hydride. Nickel ii chloride hexahydrate material safety data. It is used as a precursor to nickel boride, finely divided nickel. Safety data sheet according to 29cfr19101200 and ghs rev. Material safety data sheet copperii chloride dihydrate. Msds contains all of the information required by those regulations. Material safety data sheet nickel sulphate product information nickel sulphate synonyms. Toxicological information acute toxicity nickel chloride, hexahydrate skin not available eyes not available respiratory not available ingestion ld50 oral rat 105 mgkg carcinogenicity iarc 1.
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